Cloning LV to mirror
lvconvert --type mirror --alloc anywhere -m1 /dev/VOL/LV-orig [/dev/vdc] && lvs -a -o +devices | egrep "LV|LV-orig"
Add /dev/vdc if you want to copy to a separate Physical device, yes you need to have it in your VG…
Split mirror
lvconvert --splitmirrors 1 --name LV-copy /dev/VOL/LV-orig
Split mirror to other PV
lvconvert --splitmirrors 1 --name LV-copy /dev/VOL/LV-orig /dev/vdc
lvs -a -o +devices | egrep "LV|LV-"
lvchange -an /dev/VOL/LV-copy
lvs -a -o +devices | egrep "LV|LV-"
vgsplit VOL NEW-VOL /dev/vdc
lvs -a -o +devices | egrep "LV|LV-"
pvs
vgchange -an NEW-VOL
vgexport NEW-VOL
pvs
root@localhost:~ #